GHS Classification Result

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GENERAL INFORMATION
Item Information
CAS RN 65997-15-1
Chemical Name Portland Cement (not containing asbestos, crystalline silica < 1% )
Substance ID H27-A-013/C-013A_P
Classification year (FY) FY2015
Ministry who conducted the classification Ministry of Health, Labour and Welfare (MHLW)/Ministry of the Environment (MOE)
New/Revised New
Classification result in other fiscal year  
Download of Excel format Excel file

REFERENCE INFORMATION
Item Information
Guidance used for the classification (External link) GHS Classification Guidance for the Japanese Government (FY2013 revised edition (Ver. 1.1))
UN GHS document (External link) UN GHS document
Definitions/Abbreviations (Excel file) Definitions/Abbreviations
Model Label by MHLW (External link) MHLW Website (in Japanese Only)
Model SDS by MHLW (External link) MHLW Website (in Japanese Only)
OECD/eChemPortal (External link) eChemPortal

PHYSICAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Explosives Not applicable
-
-
- - It is estimated that there are no chemical groups present in the molecule associated with explosive properties.
2 Flammable gases (including chemically unstable gases) Not applicable
-
-
- - "Solids" according to GHS definition.
3 Aerosols Not applicable
-
-
- - Not an aerosol product.
4 Oxidizing gases Not applicable
-
-
- - "Solids" according to GHS definition.
5 Gases under pressure Not applicable
-
-
- - "Solids" according to GHS definition.
6 Flammable liquids Not applicable
-
-
- - "Solids" according to GHS definition.
7 Flammable solids Not classified
-
-
- - It is not combustible (ICSC (2001)).
8 Self-reactive substances and mixtures Not applicable
-
-
- - It is estimated that there are no chemical groups present in the molecule associated with explosive or self-reactive properties
9 Pyrophoric liquids Not applicable
-
-
- - "Solids" according to GHS definition.
10 Pyrophoric solids Not classified
-
-
- - It is not combustible (ICSC (2001)).
11 Self-heating substances and mixtures Not classified
-
-
- - It is not combustible (ICSC (2001)).
12 Substances and mixtures which, in contact with water, emit flammable gases Not classified
-
-
- - Solidifying in mixing with water is the ordinary use, and evolution of dangerous gasses is not observed at that time.
13 Oxidizing liquids Not applicable
-
-
- - "Solids" according to GHS definition.
14 Oxidizing solids Classification not possible
-
-
- - It is estimated to be an inorganic compound that does not contain halogen and contains oxygen, but the classification is not possible due to no data.
15 Organic peroxides Not applicable
-
-
- - It is an inorganic compound.
16 Corrosive to metals Classification not possible
-
-
- - No established test method suitable for solid substances.

HEALTH HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Acute toxicity (Oral) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
1 Acute toxicity (Dermal) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
1 Acute toxicity (Inhalation: Gases) Not applicable
-
-
- - "Solids" according to GHS definition.
1 Acute toxicity (Inhalation: Vapours) Not applicable
-
-
- - "Solids" according to GHS definition.
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
2 Skin corrosion/irritation Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
3 Serious eye damage/eye irritation Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
4 Respiratory sensitization Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
4 Skin sensitization Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
5 Germ cell mutagenicity Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
6 Carcinogenicity Classification not possible
-
-
- - It is reported that in multiple epidemiological studies on workers handling concrete and cement and cement plant workers who inhaled dust of this substance, increased mortality from lung cancer or cancers of other organs (bladder, stomach, colorectal cancers, and so on) or increased Standardized Incidence Ratios (SIR) was observed. On the other hand, it is reported that an increase in cancers including lung cancer and cancers of other organs was not found, and in general, results of correlation analysis between the cancer incidence and exposure concentrations are lacking (ACGIH (7th, 2010)).
Because not all study reports assessed respiratory system cancer by excluding the effects of smoking sufficiently, and because data on carcinogenic effects by exposure to this substance lack consistency and constitute insufficient evidence for A3 classification, ACGIH classified this substance (Portland Cement containing no asbestos and <1% crystalline silica) in A4 (ACGIH (7th, 2010)). Because of no carcinogenicity evaluation conducted by other international organization other than this, from the above, the substance was classified as "Classification not possible" in this hazard class due to lack of data.
7 Reproductive toxicity Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
8 Specific target organ toxicity - Single exposure Category 3 (Respiratory tract irritation)


Warning
H335 P304+P340
P403+P233
P261
P271
P312
P405
P501
It is reported that this substance is irritating to the respiratory tract (ACGIH (7th, 2010)), but no other information.
From the above, it was classified in Category 3 (respiratory tract irritation).
9 Specific target organ toxicity - Repeated exposure Category 1 (respiratory organs)


Danger
H372 P260
P264
P270
P314
P501
It is reported that in an inhalation route, benign pneumoconiosis occurs in humans, and bronchitis, dyspnea, coughing, phlegm, emphysema, and chest pains are observed. (ACGIH (7th, 2010), DFGOT vol. 11 (1998))
There is no useful information on experimental animals.
Therefore, because respiratory organs are considered to be target organs, and signs were observed in humans, the substance was classified in Category 1 (respiratory organs).
10 Aspiration hazard Classification not possible
-
-
- - Due to lack of data, the classification is not possible.

ENVIRONMENTAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Classification not possible
-
-
- - No data.
11 Hazardous to the aquatic environment (Long-term) Classification not possible
-
-
- - No data.
12 Hazardous to the ozone layer Classification not possible
-
-
- - No data.


NOTE:
* A blank or "-" in a cell of classification denotes that the classification of the hazard class was not conducted.
* Hazard_statement_and/or_Precautionary_statement will show when hovering the mouse over a code of Hazard_statement_and/or_Precautionary_statement.
Hazard_statement_and/or_Precautionary_statement are also provided in the Excel file.
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government,
and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.
* Codes assigned to each of the hazard statements and codes for each of the precautionary statement are
based on the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) in United Nations.

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