Item | Information |
---|---|
CAS number | 14915-37-8 |
Chemical name | Bis(2-sulfidopyridin-1-olato)copper |
Substance ID | 23A5182 |
Fiscal year of classification conducted | FY2011 |
Classifier(s) (Ministries) | Ministry of Health, Labour and Welfare (MHLW), Ministry of the Environment (MOE) |
New/Revised | New |
Download in Excel format | Excel file |
Item | Information |
---|---|
Guidance used for classification (External link) |
Physical Hazards & Health Hazards: GHS Classification Guidance by the Japanese Government (July, 2010)
Environmental Hazards: UN GHS Document (4th revised edition) |
Definitions / Abbreviations (Excel file) | Definitions / Abbreviations |
Model Label by MHLW (External link) | MHLW Website (in Japanese Only) |
Model SDS by MHLW (External link) | MHLW Website (in Japanese Only) |
OECD/eChemPortal (External link) | eChemPortal |
Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
---|---|---|---|---|---|---|
1 | Explosives | Classification not possible | - | - | - | There is a chemical group associated with an explosive property (N-O) present in the molecule, but the classification is not possible due to no data. |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | "Solids" according to GHS definition. |
3 | Aerosols | Not applicable | - | - | - | Not an aerosol product. |
4 | Oxidizing gases | Not applicable | - | - | - | "Solids" according to GHS definition. |
5 | Gases under pressure | Not applicable | - | - | - | "Solids" according to GHS definition. |
6 | Flammable liquids | Not applicable | - | - | - | "Solids" according to GHS definition. |
7 | Flammable solids | Classification not possible | - | - | - | No data. |
8 | Self-reactive substances and mixtures | Classification not possible | - | - | - | There is a chemical group associated with an explosive property (N-O) present in the molecule, but the classification is not possible due to no data. |
9 | Pyrophoric liquids | Not applicable | - | - | - | "Solids" according to GHS definition. |
10 | Pyrophoric solids | Classification not possible | - | - | - | No data. |
11 | Self-heating substances and mixtures | Classification not possible | - | - | - | No data. |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | It contains a metal (Cu), but it is conceivable that it does not react vigorously with water from data on the water solubility of 0.1 mg/L (Detailed Risk Assessment Report (2007) (English version)). |
13 | Oxidizing liquids | Not applicable | - | - | - | "Solids" according to GHS definition. |
14 | Oxidizing solids | Classification not possible | - | - | - | No data. |
15 | Organic peroxides | Not applicable | - | - | - | An organic compound that does not contain -O-O- structure. |
16 | Corrosive to metals | Classification not possible | - | - | - | No established test method suitable for solid substances. |
Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 4 |
H302 |
P301+P312 P264 P270 P330 P501 |
From an LD50 value of 1075 mg/kg bw for rats (RTECS (2000)) original literature: NTIS National Technical Information Service. OTS0554076), it was classified in Category 4. | |
1 | Acute toxicity (Dermal) | Not classified | - | - | - | From an LC50 value of > 2000 mg/kg bw for rabbits (RTECS (2000)) original literature: NTIS National Technical Information Service. OTS0554076), it was classified as "Not classified" in JIS classification (Category 5 or "Not classified" in UN GHS classification). |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | "Solids" according to GHS definition. |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | No data. |
1 | Acute toxicity (Inhalation: Dusts and mists) | Category 2 |
H330 |
P304+P340 P403+P233 P260 P271 P284 P310 P320 P405 P501 |
From an LC50 value of 0.07 mg/L/4h for rats (RTECS (2000) original literature: NTIS National Technical Information Service. OTS0554076), it was classified in Category 2. Besides, it was considered to be a test by dust because the LC50 value is above the saturated vapour pressure concentration (5.48E-18 mg/L). |
|
2 | Skin corrosion/irritation | Classification not possible | - | - | - | No data. |
3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | No data. |
4 | Respiratory sensitization | Classification not possible | - | - | - | No data. |
4 | Skin sensitization | Category 1 |
H317 |
P302+P352 P333+P313 P261 P272 P280 P321 P363 P501 |
Because copper and its compounds are classified as a sensitizing substance "skin; Group 2" in Japan Society for Occupational Health (Recommendations for allowable concentrations, Japan Society for Occupational Health (2011)), it was classified in Category 1. | |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | No data. |
6 | Carcinogenicity | Classification not possible | - | - | - | No data. |
7 | Reproductive toxicity | Classification not possible | - | - | - | No data. |
8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | No data. |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | No data. |
10 | Aspiration hazard | Classification not possible | - | - | - | No data. |
Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Classification not possible | - | - | - | No data. |
11 | Hazardous to the aquatic environment (Long-term) | Classification not possible | - | - | - | No data. |
12 | Hazardous to the ozone layer | Classification not possible | - | - | - | This substance is not listed in Annexes to the Montreal Protocol. |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
2016/10/31 Addition of Rationale for the classification |