GHS Classification Result
GENERAL INFORMATION
REFERENCE INFORMATION
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTES:
Updated date:
GENERAL INFORMATION
| Item | Information |
|---|---|
| CAS number | 928-96-1 |
| Chemical name | cis-3-Hexenol |
| Substance ID | 23A5073 |
| Fiscal year of classification conducted | FY2011 |
|
Classifier(s) (Ministries) |
Ministry of Health, Labour and Welfare （MHLW）, Ministry of the Environment （MOE） |
| New/Revised | New |
| Download in Excel format | Excel file |
| Item | Information |
|---|---|
|
Guidance used for classification (External link) |
Physical Hazards & Health Hazards: GHS Classification Guidance by the Japanese Government (July, 2010) Environmental Hazards: UN GHS Document （4th revised edition） |
|
Definitions / Abbreviations (Excel file) |
Definitions / Abbreviations |
|
Model Label by MHLW (External link) |
MHLW Website （in Japanese Only） |
|
Model SDS by MHLW (External link) |
MHLW Website （in Japanese Only） |
|
OECD/eChemPortal (External link) |
eChemPortal |
| Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - |
There are no chemical groups associated with explosive properties present in the molecule. |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 3 | Aerosols | Not applicable | - | - | - |
Not an aerosol product. |
| 4 | Oxidizing gases | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 5 | Gases under pressure | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 6 | Flammable liquids | Category 3 |
 |
H226 |
P303+P361+P353 P370+P378 P403+P235 P210 P233 P240 P241 P242 P243 P280 P501 |
A flash point of 54 degrees C [closed-cup] (NFPA (13th, 2006)), which is >= 23 degrees C and <= 60 degrees C, corresponds to Category 3. |
| 7 | Flammable solids | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 8 | Self-reactive substances and mixtures | Classification not possible | - | - | - |
There is a chemical group present in the molecule associated with a self-reactive property (unsaturated bond), but the classification is not possible due to no data. |
| 9 | Pyrophoric liquids | Classification not possible | - | - | - |
No data. |
| 10 | Pyrophoric solids | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 11 | Self-heating substances and mixtures | Classification not possible | - | - | - |
No established test method suitable for liquid substances. |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - |
Not containing metals or semimetals (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At). |
| 13 | Oxidizing liquids | Not applicable | - | - | - |
An organic compound that does not contain fluorine or chlorine but contains oxygen, and the oxygen is not chemically bonded to elements other than carbon or hydrogen. |
| 14 | Oxidizing solids | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 15 | Organic peroxides | Not applicable | - | - | - |
An organic compound that does not contain -O-O- structure. |
| 16 | Corrosive to metals | Classification not possible | - | - | - |
No data. |
| Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Classification not possible | - | - | - |
Lack of data. Besides, details of reported LD50 values of 4700 mg/kg bw and 7300 mg/kg bw for rats (both RTECS (2006)) from List 3 data are unknown. |
| 1 | Acute toxicity （Dermal） | Classification not possible | - | - | - |
Lack of data. Besides, details of a reported LD50 value of > 5000 mg/kg bw for rabbits (RTECS (2006)) from List 3 data are unknown. |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - |
"Liquids" according to GHS definition. |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - |
No data. |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - |
No data. |
| 2 | Skin corrosion/irritation | Classification not possible | - | - | - |
No data. |
| 3 | Serious eye damage/eye irritation | Classification not possible | - | - | - |
No data. |
| 4 | Respiratory sensitization | Classification not possible | - | - | - |
No data. |
| 4 | Skin sensitization | Classification not possible | - | - | - |
No data. |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - |
No data. |
| 6 | Carcinogenicity | Classification not possible | - | - | - |
No data. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - |
No data. |
| 8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - |
No data. |
| 9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - |
A NOEL of 1250 ppm (120 to 150 mg/kg bw/day) above a limit of a range of guidance values reported in a 98-day oral administration test by drinking water in rats (doses: 320, 1250, 5000 ppm), in which a statistically significant increase in relative kidney and adrenal weight and a slight increase in urine specific gravity with no histological signs of renal damage and no indications of abnormal kidney function were observed at 5000 ppm (ca. 625 mg/kg bw/day) (JECFA942 (1999)), corresponds to "Not classified" in an oral route. But it was classified as "Classification not possible" in specific target organ toxicity (repeated exposure) due to unknown effects from no data in other routes. |
| 10 | Aspiration hazard | Classification not possible | - | - | - |
No data. |
| Hazard class | Classification |
Pictogram (Code: symbol) Signal word |
Code (Hazard statement) |
Code (Precautionary statement) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Not classified | - | - | - |
It was classified as "Not classified" from 96-hour LC50 = 381 mg/L for fish (Pimephales promelas) (AQUIRE, 2012). |
| 11 | Hazardous to the aquatic environment （Long-term） | Not classified | - | - | - |
Reliable chronic toxicity data were not obtained. Due to not water-insoluble (water solubility = 16000 mg/L, PHYSPROP Database, 2012), and "Not classified" in acute toxicity, it was classified as "Not classified." |
| 12 | Hazardous to the ozone layer | Classification not possible | - | - | - |
This substance is not listed in Annexes to the Montreal Protocol. |
NOTES:
|
* A blank or "-" in a cell of classification denotes that the classification of the hazard class was not conducted. * Hazard_statement_and/or_Precautionary_statement will show when hovering the mouse over a code of Hazard_statement_and/or_Precautionary_statement. Hazard_statement_and/or_Precautionary_statement are also provided in the Excel file. * Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. * Codes assigned to each of the hazard statements and codes for each of the precautionary statement are based on the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) in United Nations. |
Updated date:
|
2017/3/17 Addition of Rationale for the classification |