GHS Classification Result

Chemical Name:Tributyl(methacryloyloxy)stannane
CAS:2155-70-6

Result:
ID: 1415
Classifier: Inter-ministerial Committee on GHS
Year Classified: FY2006
Reference Manual: GHS Classification Manual (10 Feb, 2006)

PHYSICAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Explosives Not applicable - - - - Containing no chemical groups with explosive properties
2 Flammable gases (including chemically unstable gases) Not applicable - - - - Classified as "liquid" or "solid" according to GHS definition
3 Aerosols Not applicable - - - - Not aerosol products
4 Oxidizing gases Not applicable - - - - Classified as "liquid" or "solid" according to GHS definition
5 Gases under pressure Not applicable - - - - Classified as "liquid" or "solid" according to GHS definition
6 Flammable liquids Classification not possible (as a liquid) - - - - No data available
7 Flammable solids Classification not possible (as a solid) - - - - No data available
8 Self-reactive substances and mixtures Classification not possible - - - - Classification not possible due to lack of data, though containing unsaturated bonds (olefin)
9 Pyrophoric liquids Classification not possible (as a liquid) - - - - No data available
10 Pyrophoric solids Classification not possible (as a solid) - - - - No data available
11 Self-heating substances and mixtures Classification not possible - - - - Test methods applicable to liquid substances are not available (the melting point is 16degC (EHC 116 (1990)) and 21.5degC (PRTR Chemicals DB (2001)) (test temperature: 140degC)).
12 Substances and mixtures which, in contact with water, emit flammable gases Classification not possible - - - - Classification not possible due to lack of data, though containing Sn (a metalloid)
13 Oxidizing liquids Classification not possible (as a liquid) - - - - Classification not possible due to lack of data, though being organic compounds containing oxygen bound to elements other than carbon and hydrogen
14 Oxidizing solids Classification not possible (as a solid) - - - - Classification not possible due to lack of data, though being organic compounds containing oxygen bound to elements other than carbon and hydrogen
15 Organic peroxides Not applicable - - - - Organic compounds containing no "-O-O-" structure
16 Corrosive to metals Classification not possible - - - - No data available

HEALTH HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Acute toxicity (Oral) Category 3 Danger H301: Toxic if swallowed P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P321: Specific treatment (see ... on this label).
P330: Rinse mouth.
P405: Store locked up.
P501: Dispose of contents/container to ...
Based on the rat LD50 (oral route) value of 160mg/kg (RTECS (2006)).
1 Acute toxicity (Dermal) Classification not possible - - - - No data available
1 Acute toxicity (Inhalation: Gases) Not applicable - - - - Due to the fact that the substance is a liquid or solid according to the GHS definition and inhalation of its gas is not expected.
1 Acute toxicity (Inhalation: Vapours) Classification not possible - - - - No data available
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible - - - - No data available
2 Skin corrosion/irritation Classification not possible - - - - No data available. As for the health hazards, refer to "ID428, Tributyl Tin Chloride, CAS: 1461-22-9."
3 Serious eye damage/eye irritation Classification not possible - - - - No data available. As for the health hazards, refer to "ID428, Tributyl Tin Chloride, CAS: 1461-22-9."
4 Respiratory sensitization Classification not possible - - - - No data available
4 Skin sensitization Classification not possible - - - - No data available
5 Germ cell mutagenicity Classification not possible - - - - No data available
6 Carcinogenicity Classification not possible - - - - No data available
7 Reproductive toxicity Classification not possible - - - - No data available
8 Specific target organ toxicity - Single exposure Classification not possible - - - - No data available. Refer to "Tributyl Tin Oxide (ID: 1275, CAS: 56-35-9)."
9 Specific target organ toxicity - Repeated exposure Classification not possible - - - - No data available. Refer to "Tributyl Tin Oxide (ID: 1275, CAS: 56-35-9)."
10 Aspiration hazard Classification not possible - - - - No data available

ENVIRONMENTAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Category 1 Warning H400: Very toxic to aquatic life P273: Avoid release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container to ...
It was classified into Category 1 from 96 hours LC50=3.2ppb of the crustacea (Mysid Shrimp)) (AQUIRE, 2003).
11 Hazardous to the aquatic environment (Long-term) Category 1 Warning H410: Very toxic to aquatic life with long lasting effects P273: Avoid release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container to ...
Since acute toxicity was Category 1 and there was no rapidly degrading (it was hydrolyzed, and triphenyltin hydroxide was generated, and was residue(existing chemical safety inspections data)), and since there was bio-accumulation (BCF=9210(triphenyltin hydroxide) (existing chemical safety inspections data)), it was classified into Category 1.


NOTE:
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.

Reference:
Reference Manual

Definitions / Abbreviations

Model Label by MHLW

MHLW Website (in Japanese Only)

Model SDS by MHLW

MHLW Website (in Japanese Only)


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