Chemical Name:Hexafluorosilicic acid
CAS:16961-83-4
ID: | 1351 |
Classifier: | Inter-ministerial Committee on GHS |
Year Classified: | FY2006 |
Reference Manual: | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | - | Liquid (GHS definition) |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not applicable | - | - | - | - | Liquid (GHS definition) |
5 | Gases under pressure | Not applicable | - | - | - | - | Liquid (GHS definition) |
6 | Flammable liquids | Not classified | - | - | - | - | Non-combustible (ICSC(J), 1995). |
7 | Flammable solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
9 | Pyrophoric liquids | Not classified | - | - | - | - | Not combustible (ICSC (J), 1995) |
10 | Pyrophoric solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Not combustible (ICSC(J) (1995)) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | This product is sold as aqueous solutions. Although smoke with a pungent odors was emitted, there is no information that flammable/combustible gases is generated. And it was made into the outside of Category. |
13 | Oxidizing liquids | Classification not possible | - | - | - | - | No data available |
14 | Oxidizing solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
16 | Corrosive to metals | Classification not possible | - | - | - | - | Although UNRTDG is classified into 8 and II according to the UNRTDG No. (1778), there is not steels or aluminum test data, and it cannot be classified. (About steel, there is also description that "Usually stored in iron containers" (Merck, 13th, 2001)). |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
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1 | Acute toxicity (Oral) | Category 4 | Warning | H302: Harmful if swallowed |
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P330: Rinse mouth. P501: Dispose of contents/container to ... |
Category 4 based on SPECIES: Rat; ENDPOINT: LD50; VALUE: 430 mg/kg; REFERENCE SOURCE: RTECS(2000), HSDB(2004) | |
1 | Acute toxicity (Dermal) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | - | Liquid (GHS definition) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible | - | - | - | - | No data available |
2 | Skin corrosion/irritation | Category 1A-1C | Danger | H314: Causes severe skin burns and eye damage |
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see ... on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to ... |
Since there was description of "corroding the skin" to humans (ICSC (2004), SITTIG (4th, 2002)), and was also classified into "C;R34 (Causes burns)" of European risk phrases, it was set as category 1A-1C. [view] It is more desirable to be set as 1A from a viewpoint of safety, when further categorizing needs to be performed. | |
3 | Serious eye damage/eye irritation | Category 1 | Danger | H318: Causes serious eye damage |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280: Wear protective gloves/protective clothing/eye protection/face protection. P310: Immediately call a POISON CENTER or doctor/physician. |
There is description which indicates caustic to the human eye (ICSC(2004), SITTIG(4th, 2002)), and it causes corrosive also to the skin. So it is set as Category 1. | |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available |
8 | Specific target organ toxicity - Single exposure | Category 2 (respiratory system (inhalation), digestive system, central nervous system) | Warning | H371: May cause damage to organs (respiratory system (inhalation), digestive system, central nervous system) |
P309+P311: IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P405: Store locked up. P501: Dispose of contents/container to ... |
Since there was a description of Priority 2 to the humans (caustic is indicated to an air passages. And pulmonary edemas may be caused by breathing vapors (ICSC (2004)), it has serious irritant in lungs, a nose, and a throat, it brings a severe obstacle in the throat and the stomach (HSDB (2004)), breathing difficulty, vomiting, nausea etc. by inhalation, and the burning sensations, the pain of a throat and an alimentary canal, a tremor, a spasm of abdominal in oral (SITTIG (4th, 2002)), and the stimulus to the skin and a respiratory tract and headache in accidental spillage from a tank car (HSDB (2004)), this product caused mild gastroenteritis by drinking the tap water which superfluous mixing (IUCLID (2000)), so it was considered as Category 2 (the respiratory systems (inhalation), digestive systems, central nervous systems). | |
9 | Specific target organ toxicity - Repeated exposure | Category 2 (tooth/bone, respiratory system) | Warning | H373: May cause damage to organs through prolonged or repeated exposure (tooth/bone, respiratory system) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Based on description on the humans of Priority 2 (bone change, the mucosal corrosivity effects (nose,throat,bronchial), pneumonia, etc. occured in long-term exposure (HSDB (2004)), and bone and tooth are affected, and fluorosis may be occured (ICSC (2004))), it was classified into Category 2 (tooth/bone,respiratory systems). | |
10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Classification not possible | - | - | - | - | Insufficient data available. |
11 | Hazardous to the aquatic environment (Long-term) | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |