Chemical Name:ethiofencarb
CAS:29973-13-5
ID: | 1137 |
Classifier: | Inter-ministerial Committee on GHS |
Year Classified: | FY2006 |
Reference Manual: | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | - | Solid (GHS definition) |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
7 | Flammable solids | Classification not possible | - | - | - | - | PM (13th, 2003) has a statement "flash point: 123degC", and it is a flammable, there is no test data, and it cannot be classified. |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
10 | Pyrophoric solids | Not classified | - | - | - | - | Flash point: 123degC (PM, 13th, 2003) and non-pyrophoric when in contact with air at a room temperature |
11 | Self-heating substances and mixtures | Classification not possible | - | - | - | - | Test methods applicable to solid (melting point <= 140degC) substances are not available. |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At). |
13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
14 | Oxidizing solids | Not applicable | - | - | - | - | Organic compounds containing oxygen and the oxygen is chemically bonded only to carbon (but not to other elements). |
15 | Organic peroxides | Not applicable | - | - | - | - | Organic compounds containing no -0-0- structure |
16 | Corrosive to metals | Classification not possible | - | - | - | - | No data available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 3 | Danger | H301: Toxic if swallowed |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment (see ... on this label). P330: Rinse mouth. P405: Store locked up. P501: Dispose of contents/container to ... |
Based on the value (227 mg/kg) calculated by using the formula based on the oral LD50 values in rats, 308, 411, 499, 200 and 200mg/kg (JMPR404 (1977), RTECS (2004) and HSDB (2004)), the substance was classified as Category 3. | |
1 | Acute toxicity (Dermal) | Category 5 | - | Warning | H313: May be harmful in contact with skin | P312: Call a POISON CENTER or doctor/physician if you feel unwell. | It was set as Category 5 based on rabbit dermal LD50 = 2500mg/kg (RTECS (2004), HSDB (2004)). |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | - | Solid (GHS definition) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible | - | - | - | - | Insufficient data available |
2 | Skin corrosion/irritation | Classification not possible | - | - | - | - | No data available |
3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | No data available |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
5 | Germ cell mutagenicity | Not classified | - | - | - | - | There is a negative result by the dominant lethal test using a mouse (JMPR404 (1977)), and other in vivo data not being found. So it carried out the outside of Category according to classification guidelines. In addition, weak positive finding is accepted in the Salmonella test (JMPR584 (1982)). |
6 | Carcinogenicity | Classification not possible | - | - | - | - | By the experiment using rat, it is suggested that this product has tumor promotions activity (HSDB (2004)), but there is no data of the carcinogenicity of this product, and data is insufficient. Therefore, it cannot be classified. |
7 | Reproductive toxicity | Not classified | - | - | - | - | In the teratogenicity study or three-generation reproduction studies using rats or rabbits, effects was not seen in reproductive potential and development, in partly, the slight effect on bone was seen (JMPR584 (1982), JMPR404 (1977)). So it carried out the outside of Category. |
8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | - | Although inhibition of cerebellar and hematological cholinesterase inhibition of the activity are observed with administration of this product in a rat (JMPR404 (1977)), there is no data which indicates the toxic effects and it cannot be classified due to insufficient data. |
9 | Specific target organ toxicity - Repeated exposure | Category 2 (liver) | Warning | H373: May cause damage to organs through prolonged or repeated exposure (liver) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Since as the result in the repeated administration with dose being equivalent to Category 2 with a guidance value to the rat or the dog, the influence such as the increase in liver weights, hypertrophy of liver, or swelling of hepatocyte was observed (JMPR404 (1977)), it was classified into Category 2 (liver). | |
10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Category 1 | Warning | H400: Very toxic to aquatic life |
P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to ... |
It was classified into Category 1 from 48-hour LC50=0.22mg/L of Crustacea (Water fleas) (HSDB, 2004). | |
11 | Hazardous to the aquatic environment (Long-term) | Category 1 | Warning | H410: Very toxic to aquatic life with long lasting effects |
P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to ... |
Classified into Category 1, since acute toxicity was Category 1, supposed not rapidly degrading (BIOWIN), though supposed less bioaccumulative (log Kow=2.04 (PHYSPROP Database, 2005)). |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |