GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：barium tetracyanoplatinate
CAS：562-81-2
Result：
| ID: | 1042 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
| 6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 7 | Flammable solids | Not classified | - | - | - | - | Not classified because it is considered as non-combustible substances structurally |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
| 9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 10 | Pyrophoric solids | Not classified | - | - | - | - | Not classified because it is considered as Non-combustible substances structurally |
| 11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Not classified because it is considered as non-combustible substances structurally |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | Stable to water. (As for tetrahydrate of this substance, aqueous solubility values is acquired.) |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 14 | Oxidizing solids | Not applicable | - | - | - | - | Inorganic compounds containing no oxygen and halogen. |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Dermal） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | No data available |
| 2 | Skin corrosion/irritation | Category 3 | - | Warning | H316: Causes mild skin irritation | P332+P313: If skin irritation occurs: Get medical advice/attention. | There is no data of this product. But the water-soluble barium compounds are supposed to indicate skin irritation (ACGIH-TLV (2006)). Since there is description that each of barium (107 EHC (J), 1990) and cyanide (61 CICAD (J), 2004) indicate mild skin irritations, it was set to Category 3. |
| 3 | Serious eye damage/eye irritation | Category 2A-2B |
|
Warning | H319: Causes serious eye irritation |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. |
There is no this product data. But in ACGIH-TLV (2006), the water-soluble barium compounds irritates to the eye. There are the descriptions that barium (107 EHC (J), 1990) shows severe eye irritation, cyanide (61 CICAD (J), 2004) shows slight eye irritation, and platinum compound (125 EHC (J), 1991) shows eye irritation. From the above information, it is difficult to be subdivide, and it was classified into Category 2A-2B. |
| 4 | Respiratory sensitization | Category 1 |
|
Danger | H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled |
P304+P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P285: In case of inadequate ventilation wear respiratory protection. P501: Dispose of contents/container to ... |
Although there was no data for this substance, water-soluble platinum salt was classified as Category 1 according to Japan Society for Occupational Health advice (2005). Since platinum was indicated as the respiratory allergic substance by the Japanese Society of Occupational Allergy meeting, we classified it to be Category 1. |
| 4 | Skin sensitization | Category 1 |
|
Warning | H317: May cause an allergic skin reaction |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment （see ... on this label）. P363: Wash contaminated clothing before reuse. P501: Dispose of contents/container to ... |
Although there is no data of this substance, water-soluble platinum salt is classified into 1 according to Association of Industrial Health (2005). Since platinum was used as the skin sensitization by the Japanese Society of Occupational Allergy, it was set to Category 1. |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | Without data. In addition, in CICAD (J)61 (2004) and PIM G003 (WHO/ICPS, 1997), it is supposed that there is no mutagenic in a cyanide. |
| 6 | Carcinogenicity | Classification not possible | - | - | - | - | There is no data about this product. A water-soluble barium compounds (ACGIH-TLV, 2006) are equivalent to out of Category (A4), but the carcinogenicity evaluation of platinum salts is not sufficient (EHC (J), 125, 1991). So it cannot be classified due to insufficient data. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | There is no this product data, and although the description that "cyanide induces adverse effect against development only by the given dose or concentration which has toxicity in dam clearly" exists in CICAD (J) 61(2004). Since data is insufficient, it cannot be classified. |
| 8 | Specific target organ toxicity - Single exposure | Category 1 (cardiovascular system, respiratory system, central nervous system, skeletal muscle) |
|
Danger | H370: Causes damage to organs (cardiovascular system, respiratory system, central nervous system, skeletal muscle) |
P307+P311: IF exposed: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment （see ... on this label）. P405: Store locked up. P501: Dispose of contents/container to ... |
There are no data for this substance. But the cardio-vascular system, respiratory system and central nervous system are listed as the target organs of the acute toxicity of the cyanide (CICAD (J), 61, 2004), and the cardio-vascular system and skeletal muscle as the target organs of the aqueous barium compound (possibly the effect of hypokalemia). The substance was classified as Category 1 (cardio-vascular system, respiratory system, central nervous system, skeletal muscle) because each source reference is a Priority 1 document. |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (central nervous system) |
|
Danger | H372: Cause damage to organs through prolonged or repeated exposure (central nervous system) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Although there was no data about this product, we classified it into Category 1(central nervous system) based on the description that repeated exposure of cyanide affects the central nervous systems (CICAD(J)61 (2004; Priority 1 document)). |
| 10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | No data available |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | No data available. |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website （in Japanese Only） |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |