GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：disodium tri(cyano-C)cuprate(2-)
CAS：14264-31-4
Result：
| ID: | 1041 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
| 6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 7 | Flammable solids | Not classified | - | - | - | - | Not classified because of UNRTDG No. 2316, Class: 6.1, PG I (not Class: 4.1) |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
| 9 | Pyrophoric liquids | Not classified | - | - | - | - | Solid (GHS definition) |
| 10 | Pyrophoric solids | Not classified | - | - | - | - | Not classified because of UNRTDG No. 2316, Class: 6.1, I (not Class: 4.2) |
| 11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Not classified because of UNRTDG No. 2316 Class: 6.1, PG I (not Class: 4.2) |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | UNRTDG corresponding to the U.N. number (2316) peculiar to a substance is classified into 6.1 and I. Since 4.3 which indicates a water reactions combustibles was not attached, it carried out the outside of Category. |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 14 | Oxidizing solids | Not applicable | - | - | - | - | Inorganic compounds containing no oxygen and halogen. |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Classification not possible | - | - | - | - | Without data. [Note] The data about the healthy hazardous property of this substance was not found. But the substance is cyanide, and it is consider that it contains high toxicity. Also refer to the classification result of the relative substances of sodium cyanide (ID No.0028, CAS No.143-33-9) and copper cyanides (ID No.0273, CAS No.544-92-3). |
| 1 | Acute toxicity （Dermal） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | No data available |
| 2 | Skin corrosion/irritation | Category 3 | - | Warning | H316: Causes mild skin irritation | P332+P313: If skin irritation occurs: Get medical advice/attention. | There is no data of this product. But there is description that cyanide has weak skin irritations (CICAD(J)61(2004)), and it was set to Category 3. |
| 3 | Serious eye damage/eye irritation | Category 2B | - | Warning | H320: Causes eye irritation |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P264: Wash ... thoroughly after handling. |
There was no data about this product. But cyanide irritaties weakly to the eye in CICAD(J)61 (2004). So it was classified into Category 2B. |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
| 4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | Without data. In addition, it is supposed in CICAD (J)61 (2004) and PIM G003 (WHO/ICPS, 1997) that there is no mutagenic in cyanide. |
| 6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | There is no this product data, and although the description that "cyanide induces adverse effect against development only by the given dose or concentration which has toxicity in dam clearly" exists in CICAD (J) 61(2004). Since data is insufficient, it cannot be classified. |
| 8 | Specific target organ toxicity - Single exposure | Category 1 (cardiovascular system, respiratory system, central nervous system) |
|
Danger | H370: Causes damage to organs (cardiovascular system, respiratory system, central nervous system) |
P307+P311: IF exposed: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment （see ... on this label）. P405: Store locked up. P501: Dispose of contents/container to ... |
There are no data for this substance. But CICAD (J) 61(2004), a Priority 1 document, lists the cardio-vascular system, respiratory system and central nervous system as the target organs of the cyanide of the substance in acute toxicity tests. The substance was classified as Category 1 (cardio-vascular system, respiratory system, central nervous system). |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (central nervous system) |
|
Danger | H372: Cause damage to organs through prolonged or repeated exposure (central nervous system) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Although there was no data about this product, we classified it into Category 1(central nervous system) based on the description that repeated exposure of cyanide affects the central nervous systems (CICAD(J)61 (2004; Priority 1 document)). |
| 10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | No data available |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | No data available. |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website （in Japanese Only） |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |