Chemical Name:carbonyl difluoride
CAS:353-50-4
ID: | 920 |
Classifier: | Inter-ministerial Committee on GHS |
Year Classified: | FY2006 |
Reference Manual: | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
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1 | Explosives | Not applicable | - | - | - | - | Gas (GHS definition) |
2 | Flammable gases (including chemically unstable gases) | Not classified | - | - | - | - | Non-combustible (ICSC(J), 2003) |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not classified | - | - | - | - | Not classified in UNRTDG Subsidiary risks Class: 5.1 |
5 | Gases under pressure | Liquefied gas | Warning | H280: Contains gas under pressure; may explode if heated | P410+P403: Protect from sunlight. Store in a well-ventilated place. | Compressed liquedfied gas according to a report, though the critical temprature is unknown (ICSC(J), 2003) | |
6 | Flammable liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
7 | Flammable solids | Not applicable | - | - | - | - | Gas (GHS definition) |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | Gas (GHS definition) |
9 | Pyrophoric liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
10 | Pyrophoric solids | Not applicable | - | - | - | - | Gas (GHS definition) |
11 | Self-heating substances and mixtures | Not applicable | - | - | - | - | Gas (GHS definition) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | Gas (GHS definition) |
13 | Oxidizing liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
14 | Oxidizing solids | Not applicable | - | - | - | - | Gas (GHS definition) |
15 | Organic peroxides | Not applicable | - | - | - | - | Gas (GHS definition) |
16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to gas substances are not available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Not applicable | - | - | - | - | Gas (GHS definition) |
1 | Acute toxicity (Dermal) | Not applicable | - | - | - | - | Gas (GHS definition) |
1 | Acute toxicity (Inhalation: Gases) | Category 2 | Danger | H330: Fatal if inhaled |
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P284: Wear respiratory protection. P310: Immediately call a POISON CENTER or doctor/physician. P320: Specific treatment is urgent (see ... on this label). P405: Store locked up. P501: Dispose of contents/container to ... |
It was considered as Category 2 based on the lower value from rat LC50 (1 hour) value= 360ppm (4-hour equivalent of 180ppm), and 460ppm (4-hour equivalent of 230ppm) (ACGIH 7th, 2001, PATTY 4th, 1994). | |
1 | Acute toxicity (Inhalation: Vapours) | Not applicable | - | - | - | - | Gas (GHS definition) |
1 | Acute toxicity (Inhalation: Dusts and mists) | Not applicable | - | - | - | - | Gas (GHS definition) |
2 | Skin corrosion/irritation | Category 2 | Warning | H315: Causes skin irritation |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment (see ... on this label). P362: Take off contaminated clothing and wash before reuse. |
It was set as Category 2 from description that the skin was stimulated (ICSC (J)(2003), HSDB (2005), HSFS (1999), SITTIG (4th, 2002)). | |
3 | Serious eye damage/eye irritation | Category 2A-2B | Warning | H319: Causes serious eye irritation |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. |
We classified it as Category 2A-2B based on the descriptions that it stimulated the eyes (ICSC (J) (2003), HSDB (2005), HSFS (1999), and SITTIG (4th, 2002)). | |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data available |
6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available |
8 | Specific target organ toxicity - Single exposure | Category 1 (lung) | Danger | H370: Causes damage to organs (lung) |
P307+P311: IF exposed: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment (see ... on this label). P405: Store locked up. P501: Dispose of contents/container to ... |
It was set as Category 1 (pneumoconiosiss) from description in ACGIH (7th, 2001) that pulmonary edemas was seen at the concentration of the guidance value range of Category 1 in the single inhalation exposure tests using rats. | |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | No data available |
10 | Aspiration hazard | Not applicable | - | - | - | - | Gas (GHS definition) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Classification not possible | - | - | - | - | No data available |
11 | Hazardous to the aquatic environment (Long-term) | Classification not possible | - | - | - | - | No data available. |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model SDS by MHLW |
MHLW Website (in Japanese Only) |