Chemical Name:Bromochlorodifluoromethane; Halone-1211
CAS:353-59-3
ID: | 482 |
Classifier: | Inter-ministerial Committee on GHS |
Year Classified: | FY2006 |
Reference Manual: | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
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1 | Explosives | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
2 | Flammable gases (including chemically unstable gases) | Not classified | - | - | - | - | Non-flammable (ICSC, 1999) |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not classified | - | - | - | - | Classified into Division 2.2 (UN#1974) (UN Recommendations on the Transport of Dangerous Goods) |
5 | Gases under pressure | Liquefied gas | Warning | H280: Contains gas under pressure; may explode if heated | P410+P403: Protect from sunlight. Store in a well-ventilated place. | The boiling point is -4degC (ICSC (1999)), and the critical temperature is 154degC (Lide (84th, 2003)), i.e., "Liquefied gas." Classified into Division 2.2 (UN#1974) (UN Recommendations on the Transport of Dangerous Goods) | |
6 | Flammable liquids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
7 | Flammable solids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
9 | Pyrophoric liquids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
10 | Pyrophoric solids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
11 | Self-heating substances and mixtures | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
13 | Oxidizing liquids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
14 | Oxidizing solids | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
15 | Organic peroxides | Not applicable | - | - | - | - | Classified as "gas" according to GHS definition |
16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to gaseous substances are not available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
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1 | Acute toxicity (Oral) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Dermal) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Gases) | Not classified | - | - | - | - | Based on the rat LC50 (4 hour inhalation) value of 31,300ppm representing the lower of the two testing data, 31,300ppm and 50,000ppm (IUCLID (2000)). |
1 | Acute toxicity (Inhalation: Vapours) | Not applicable | - | - | - | - | Due to the fact that the substance is "gas" according to the GHS definition and inhalation of its vapour is not expected. |
1 | Acute toxicity (Inhalation: Dusts and mists) | Not applicable | - | - | - | - | Due to the fact that the substance is "gas" according to the GHS definition and inhalation of its dust/mist is not expected. |
2 | Skin corrosion/irritation | Classification not possible | - | - | - | - | No data available |
3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | No data available |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data available |
6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available |
8 | Specific target organ toxicity - Single exposure | Category 1 (heart), Category 2 (nervous system, blood system), Category 3 (narcotic effects, respiratory tract irritation) |
Danger Warning |
H370: Causes damage to organs (heart) H371: May cause damage to organs (nervous system, blood system) H336: May cause drowsiness or dizziness (narcotic effects, respiratory tract irritation) H335: May cause respiratory irritation (narcotic effects, respiratory tract irritation) |
P307+P311: IF exposed: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment (see ... on this label). P405: Store locked up. P501: Dispose of contents/container to ... P309+P311: IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P312: Call a POISON CENTER or doctor/physician if you feel unwell. |
Based on the human evidence: "cardio-effects occur during exercise" (PATTY (4th, 1999)), "brain edema, methemoglobin " "recovery from dizziness and paresthesia" (HSDB (1999)), "Bromochlorodifluoromethane irritates the eye, nose and throat" (HSFS (1998)). Also based on the evidence from animal studies: "Slight tremors characterized the clinical toxicity after 12 minutes. All mice recovered very rapidly following cessation of exposure" (HSDB (1999)). | |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | Insufficient data available |
10 | Aspiration hazard | Not applicable | - | - | - | - | Not applicable |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Classification not possible | - | - | - | - | No data available |
11 | Hazardous to the aquatic environment (Long-term) | Classification not possible | - | - | - | - | No data available |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |