GHS Classification Result

Chemical Name:Sodium tridecylbenzenesulphonate (C13)
CAS:26248-24-8

Result:
ID: 348
Classifier: Inter-ministerial Committee on GHS
Year Classified: FY2006
Reference Manual: GHS Classification Manual (10 Feb, 2006)

PHYSICAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Explosives Not applicable - - - - Containing no chemical groups with explosive properties
2 Flammable gases (including chemically unstable gases) Not applicable - - - - Classified as "solid" according to GHS definition
3 Aerosols Not applicable - - - - Not aerosol products
4 Oxidizing gases Not applicable - - - - Classified as "solid" according to GHS definition
5 Gases under pressure Not applicable - - - - Classified as "solid" according to GHS definition
6 Flammable liquids Not applicable - - - - Classified as "solid" according to GHS definition
7 Flammable solids Classification not possible - - - - No data available
8 Self-reactive substances and mixtures Classification not possible - - - - Classification not possible due to lack of data, though being sulfonyls, containing chemical groups with self-reactive properties
9 Pyrophoric liquids Not applicable - - - - Classified as "solid" according to GHS definition
10 Pyrophoric solids Not classified - - - - Considered non-pyrophoric when in contact with air at ordinary temperatures since the substance is used as laundry detergents (CERI-NITE Hazard Assessment, 2006), and sodium dodecylbenzenesulphonate (C12), which is an analog, is classified as non-flammable (ICSC, 1999).
11 Self-heating substances and mixtures Classification not possible - - - - As for a liquid or solid with melting point of <140degC, classification is not possible since test methods applicable to liquid substances are not available (test temperature: 140degC), whereas for those with melting point of >140degC, classification is not possible due to lack of data. However, the substance can be non-flammable and thus "Not classified" since sodium dodecylbenzenesulphonate (C12), which is an analog, is classified as non-flammable (ICSC, 1999).
12 Substances and mixtures which, in contact with water, emit flammable gases Not classified - - - - Stable to water (used as laundry detergents (CERI-NITE Hazard Assessment, 2006))
13 Oxidizing liquids Not applicable - - - - Classified as "solid" according to GHS definition
14 Oxidizing solids Classification not possible - - - - Classification not possible due to lack of data, though being organic compounds containing oxygen bound to the elements other than carbon and hydrogen.
15 Organic peroxides Not applicable - - - - Organic compounds containing no "-O-O-" structure
16 Corrosive to metals Classification not possible - - - - As for those with melting point of >55degC, classification is not possible since test methods applicable to solid substances are not available, whereas as for those with melting point of <55degC, classification is not possible due to lack of data. However, the substance can be included in "Not classified" since it is widely used as laundry detergents (CERI-NITE Hazard Assessment, 2006).

HEALTH HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Acute toxicity (Oral) Category 4 Warning H302: Harmful if swallowed P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P330: Rinse mouth.
P501: Dispose of contents/container to ...
Based on the rat LD50 (oral route) value of 1,460mg/kg representing the lower of the two testing data, 1,460mg/kg (males) and 1,470mg/kg (females) (CERI-NITE Hazard Assessment No.5 (2005)) (LAS-Na mixtures with carbon chain lengths of 10-14; no data available on sodium tridecylbenzenesulphonate per se).
1 Acute toxicity (Dermal) Classification not possible - - - - No data available
1 Acute toxicity (Inhalation: Gases) Not applicable - - - - Due to the fact that the substance is "solid" according to the GHS definition and inhalation of its gas is not expected. Note: The substance is considered solid since sodium dodecylbenzenesulphonate (C12) is solid (IPCS 1470 (2002)).
1 Acute toxicity (Inhalation: Vapours) Classification not possible - - - - No data available
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible - - - - No data available
2 Skin corrosion/irritation Category 2 Warning H315: Causes skin irritation P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P264: Wash ... thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P362: Take off contaminated clothing and wash before reuse.
Based on the description in the report on human epidemiological studies (CERI-NITE Hazard Assessment No.5 (2005)): "24 hour application of 1% aqueous solution of LAS induced moderate irritation." The substance is thus considered a moderate irritant (LAS mixtures with carbon chain lengths of 10-14; no data available on sodium tridecylbenzenesulphonate per se).
3 Serious eye damage/eye irritation Category 2A Warning H319: Causes serious eye irritation P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P264: Wash ... thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Based on the description in the report on rabbit eye irritation tests (CERI-NITE Hazard Assessment No.5 (2005)): "Application of 5% solution produced severe congestion and edema." The substance is thus considered a severe irritant (LAS mixtures with C11-13; no data available on sodium tridecylbenzenesulphonate per se).
4 Respiratory sensitization Classification not possible - - - - No data available
4 Skin sensitization Category 1 Warning H317: May cause an allergic skin reaction P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to ...
Based on the description in the report on guinea pig skin sensitization tests (CERI Hazard Data 2001-20 (2002) and CERI-NITE Hazard Assessment No.5 (2004)): "Skin sensitization: positive" (linear alkylbenzenesulfonate and its salts (the carbon chain length unknown); No data available on sodium tridecylbenzenesulphonate per se).
5 Germ cell mutagenicity Classification not possible - - - - Classification not possible due to the insufficiency of data (no definite data are available regarding sodium tridecylbenzenesulphonate per se). As for linear alkylbenzene sulphonate (LAS) and its salts [carbon chain lengths of 10-14 and their mixtures], no data are available on germ cell mutagenicity tests in vivo, whereas multi-generation mutagenicity tests (dominant lethal tests), somatic cell mutagenicity tests in vivo (micronucleus tests, chromosome aberration tests) and Ames assay gave negative results, described in NTP DB (Access on June, 2006), CERI-NITE Hazard Assessment No.5 (2005) and EHC 169 (1996).
6 Carcinogenicity Classification not possible - - - - Classification not possible based on expert judgment in the absence of existing classification together with the absence of definite data on sodium tridecylbenzenesulphonate per se. CERI-NITE Hazard Assessment No.5 (2005) presents some data regarding carcinogenicity studies on linear alkylbenzene sulphonate (LAS) and its salts [carbon chain lengths of 10-14 and their mixtures].
7 Reproductive toxicity Classification not possible - - - - Classification not possible due to the insufficiency of data (no definite data are available regarding sodium tridecylbenzenesulphonate per se). As for linear alkylbenzene sulphonate (LAS) and its salts [carbon chain lengths of 10-14 and their mixtures], there was no evidence of adverse effects on the parental animals and the offspring observed in oral studies, whereas decreased fertility and increased incidence of malformation in the offspring were observed at doses inducing parental toxicity in dermal studies, described in CERI-NITE Hazard Assessment No.5 (2005) and EHC 169 (1996).
8 Specific target organ toxicity - Single exposure Classification not possible - - - - Classification not possible in the absence of data on sodium tridecylbenzenesulphonate per se. Note: As for linear alkylbenzene sulphonate (LAS) and its salts [carbon chain lengths of 10-14 and their mixtures], "clinical symptoms include confusion, vomiting, pharyngal and oral pains, and the tendency of blood pressure to decrease" (NITE Initial Risk Assessment No.5 (2005)).
9 Specific target organ toxicity - Repeated exposure Classification not possible - - - - Classification not possible due to the fact that the only available data are those for mixtures of C10-14.
10 Aspiration hazard Classification not possible - - - - No data available

ENVIRONMENTAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Category 2 - - H401: Toxic to aquatic life P273: Avoid release to the environment.
P501: Dispose of contents/container to ...
It was classified into Category 2 from 48 hours LC50=2.0mg/L of the crustacea (Daphnia magna) (EHC169 (1996) and others.).
11 Hazardous to the aquatic environment (Long-term) Not classified - - - - Since there was rapidly degrading (the decomposition of p-n-dodecylbenzenesulfonic acid sodium salt by BOD: 73% (Existing Chemical Safety Inspections Data)) and the bio-accumulation was low (log Kow=2.52(PHYSPROP Database, 2005)), it was claasified into Not classified.


NOTE:
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.

Reference:
Reference Manual

Definitions / Abbreviations

Model Label by MHLW

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Model SDS by MHLW

MHLW Website (in Japanese Only)


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